6-AZABICYCLO[3.1.0]HEX-3-EN-2-OL DERIVATIVES, PHOTOCHEMICALLY GENERATED BUILDING-BLOCKS FOR BICYCLIC BETA-LACTAMS

Authors
GLARNER F THORNTON SR SCHARER D BERNARDINELLI G BURGER U
Citation
F. Glarner et al., 6-AZABICYCLO[3.1.0]HEX-3-EN-2-OL DERIVATIVES, PHOTOCHEMICALLY GENERATED BUILDING-BLOCKS FOR BICYCLIC BETA-LACTAMS, Helvetica Chimica Acta, 80(1), 1997, pp. 121-127
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Helvetica Chimica Acta → ACNP
ISSN journal
0018019X
Volume
80
Issue
1
Year of publication
1997
Pages
121 - 127
Database
ISI
SICI code
0018-019X(1997)80:1<121:6DPG>2.0.ZU;2-T
Abstract
The title compounds 4 are obtained by photolysis of simple N-alkylpyri dinium salts in H2O or alcohol. On reaction with [Fe-2(CO)(9)] in THF, 4 gives bicyclic tricarbonyliron complexes 13a-d, which on oxidative decomplexation with eerie ammonium nitrate afford cis-fused cyclopente no-beta-lactams 15a-d.