LIQUID-VAPOR-EQUILIBRIUM IN THE WATER PIPERIDINE PYRIDINE SYSTEM

Authors
MITROPOLSKAYA VA MOZZHUKHIN AS FLER GA
Citation
Va. Mitropolskaya et al., LIQUID-VAPOR-EQUILIBRIUM IN THE WATER PIPERIDINE PYRIDINE SYSTEM, Russian journal of applied chemistry, 66(4), 1994, pp. 769-772
Citations number
8
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
66
Issue
4
Year of publication
1994
Part
2
Pages
769 - 772
Database
ISI
SICI code
1070-4272(1994)66:4<769:LITWPP>2.0.ZU;2-G
Abstract
The liquid - vapor equilibrium in the piperidine-water, piperidine-pyr idine, and water-piperidine-pyridine systems has been investigated by ebulliometric titration. Binary and tertiary azeotropes were shown to be missing in the two latter systems. A mathematical model of liquid - vapor equilibrium, based on the Tsuboka-Katayama equation has been ob tained. Investigation of the model has shown that within the pressure range 0.066-5.0 atm only aqueous piperidine and the pyridine azeotrope s exist in the ternary system.