GAS-PHASE REACTIVITY OF TRANSITION-METAL CATIONS WITH CYANOGEN RADICAL PRECURSORS

Authors
SABLIER M CAPRON L MESTDAGH H ROLANDO C
Citation
M. Sablier et al., GAS-PHASE REACTIVITY OF TRANSITION-METAL CATIONS WITH CYANOGEN RADICAL PRECURSORS, Tetrahedron letters, 35(18), 1994, pp. 2895-2898
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
18
Year of publication
1994
Pages
2895 - 2898
Database
ISI
SICI code
0040-4039(1994)35:18<2895:GROTCW>2.0.ZU;2-N
Abstract
First row transition metal cations M(+) react in the gas phase with XC N (X = Br, I) leading mainly to MCN(+) and MX(+). The M(+)-CN bond ene rgy is shown to exceed 230 kJ mol(-1) for most metals.