SELECTIVE BROMOCHLORINATION OF OMOTRICYCLO[5.2.1.0(2,6)]DECA-3,8-DIENE-5,10-DIONE 10-ETHYLENE ACETAL AT THE CONJUGATED CARBON-CARBON DOUBLE-BOND

Authors
GABLE RW PARKER KJ TSANAKTSIDIS J
Citation
Rw. Gable et al., SELECTIVE BROMOCHLORINATION OF OMOTRICYCLO[5.2.1.0(2,6)]DECA-3,8-DIENE-5,10-DIONE 10-ETHYLENE ACETAL AT THE CONJUGATED CARBON-CARBON DOUBLE-BOND, Australian Journal of Chemistry, 47(5), 1994, pp. 963-968
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
47
Issue
5
Year of publication
1994
Pages
963 - 968
Database
ISI
SICI code
0004-9425(1994)47:5<963:SBOO>2.0.ZU;2-A
Abstract
Exposure of (1) to bromine in thionyl chloride/dimethylformamide produ ced (5), the result of regio- and stereo-selective addition of bromine chloride across the carbonyl-conjugated double bond. The structure of (5) was determined by X-ray crystallography, and its mode of formatio n is discussed in terms of the carbonyl attack mechanism. [