Ai. Marshakov et al., STUDY OF THE DISCHARGE OF HYDROXONIUM IONS AND HYDROGEN PENETRATION INTO IRON UNDER ANODIC POLARIZATION CONDITIONS, Protection of metals, 29(6), 1993, pp. 707-716
Features of the discharge of H3O+ and hydrogen penetration into metal
in the range of active dissolution potentials for Fe in acid sulfate e
lectrolytes, and also in the presence of anions F-, [Fe(CN)6]4-, HS-,
CNS- and a number of oxygen-containing oxidizing agents are studied. E
xperimental results are interpreted quantitatively on the basis of ide
as about the effect of Fe ionization processes on the degree of electr
ode surface filling by H3O+ ions.