CRYSTAL-CHEMISTRY OF NI3ASVO8 AND CO3ASVO 8

Authors
OSTERLOH D MULLERBUSCHBAUM H
Citation
D. Osterloh et H. Mullerbuschbaum, CRYSTAL-CHEMISTRY OF NI3ASVO8 AND CO3ASVO 8, Journal of alloys and compounds, 206(2), 1994, pp. 255-258
Citations number
16
Categorie Soggetti
Chemistry Physical","Metallurgy & Mining","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
206
Issue
2
Year of publication
1994
Pages
255 - 258
Database
ISI
SICI code
0925-8388(1994)206:2<255:CONAC8>2.0.ZU;2-9
Abstract
Investigations of Ni3AsVO8 (I) and Co3AsVO8 (II) by X-ray single cryst al technique show that (I) and (II) are isotypic to Co3V2O8. They crys tallize with orthorhombic symmetry, space group D2h18-Cmca, Z = 4. The lattice constants are (I): a = 5.932; b = 11.324; c = 8.197 angstrom (II): a = 6.021; b = 11.456; c = 8.266 angstrom. The point position of the M5+ ions is occupied by As5+ and V5+ statistically.