Ib. Sladkov, CALCULATION OF THE PHYSICOCHEMICAL PROPERTIES OF INORGANIC MOLECULAR-COMPOUNDS BY METHODS OF THE THEORY OF THERMODYNAMIC SIMILARITY, Russian journal of applied chemistry, 66(5), 1993, pp. 801-806
Methods for calculating physicochemical properties, based on the three
-parameter form of the law of corresponding states, are considered. A
dimensionless parameter that is dependent on the complexity of the mol
ecular geometry and on the polarity of the chemical bond is proposed a
s a principal criterion of thermodynamic similarity. The accuracy of t
he methods presented is compared to that of the methods for approximat
e calculation of the physicochemical properties, described in the lite
rature.