D. Glasser et al., THE ATTAINABLE REGION FOR SEGREGATED, MAXIMUM MIXED, AND OTHER REACTOR MODELS, Industrial & engineering chemistry research, 33(5), 1994, pp. 1136-1144
It is common practice in process synthesis to choose a reactor structu
re and use the free parameters associated with it to optimize the syst
em. It is of some importance to assess how effective such an approach
is. A geometric (attainable region) approach is used to find the bound
s on the performance of reactor systems, and these are compared with t
he complete attainable region. It is shown for instance that the conve
rsions obtained in segregated and maximimum mixed reactors are not gen
eral bounds on conversion. Even two or more environment reactor models
need not be sufficiently general to provide bounds on conversion. Giv
en a proposed reactor system, it is thus possible to compare the achie
vable conversions with those of the complete attainable region. This p
rovides a useful test to determine whether significant improvements in
reactor performance can be obtained by using alternative reactor stru
ctures.