W. Uhlig et C. Tretner, SYNTHESIS AND REACTIVITY OF TRIFLATE SUBS TITUTED SILOXANE DERIVATIVES, Zeitschrift fur anorganische und allgemeine Chemie, 620(5), 1994, pp. 939-943
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
The reaction of amino substituted siloxane derivatives with trifluorom
ethanesulfonic acid leads under elimination of ammonium trifluorometha
nesulfonate to the formation of siloxanyl triflates. The compounds are
characterised by NMR-spectroscopy (Si-29, C-13, H-1). The synthetic p
otential of these siloxanes is shown on selected examples. One interes
ting point of view is the synthesis of silicon containing oligo- and p
olymeres, in which siloxane and silylenealkine units are combined.