SYNTHESIS AND CRYSTAL STRUCTURAL STUDY OF TERNARY MOLYBDATE NAMG3IN(MOO4)5

Authors
KLEVTSOVA RF VASILIEV AD KOZHEVNIKOVA NM GLINSKAYA LA KRUGLIK AI KOTOVA IY
Citation
Rf. Klevtsova et al., SYNTHESIS AND CRYSTAL STRUCTURAL STUDY OF TERNARY MOLYBDATE NAMG3IN(MOO4)5, Journal of structural chemistry, 34(5), 1993, pp. 784-788
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
34
Issue
5
Year of publication
1993
Pages
784 - 788
Database
ISI
SICI code
0022-4766(1993)34:5<784:SACSSO>2.0.ZU;2-V
Abstract
We have synthesized single crystals of a ternary molybdate NaMg3In(MoO 4)5 and carried out an X-ray structural study (a KM-4 automatic diffra ctometer, MoK(alpha) radiation, 4503 F, R = 0.047). The triclinic unit cell dimensions are a = 7.0476(7), b = 17.935(2), c = 6 9849(7) angst rom, alpha = 87.650(9), beta = 100.980(8), gamma = 92.510(9)-degrees, V = 865.5(2) angstrom3, Z = 2, and space group P1BAR. The crystal stru cture involves MoO4 tetrahedra and (Mg. In)06 octahedra forming a thre e-dimensional framework with Na atoms located in its cavities. The com pound melts at 990-degrees-C with decomposition.