K. Aho et al., FUEL NITROGEN RELEASE DURING BLACK LIQUOR PYROLYSIS .1. LABORATORY MEASUREMENTS AT DIFFERENT CONDITIONS, Tappi journal, 77(5), 1994, pp. 121-127
Fuel nitrogen release during black liquor pyrolysis is high. There is
only minor release during the drying stage. Ammonia is the main fixed
nitrogen species formed. The rate of fixed nitrogen release increases
with increasing temperature. The level of fixed nitrogen released by b
irch liquor is almost twice the level for pine liquor. Assuming comple
te conversion to NO, fixed nitrogen yields gave NO concentrations near
typically measured values for flue gases in full scale recovery boile
rs.