IODINE INTERCALATION IN BI2SR2Y0.5CA0.5CU2O8- EVIDENCE OF HOLE TRANSFER FROM IODINE TO COPPER-OXYGEN SHEETS(DELTA )

Authors
SUBRAMANIAN MA
Citation
Ma. Subramanian, IODINE INTERCALATION IN BI2SR2Y0.5CA0.5CU2O8- EVIDENCE OF HOLE TRANSFER FROM IODINE TO COPPER-OXYGEN SHEETS(DELTA ), Journal of solid state chemistry, 110(1), 1994, pp. 193-195
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
110
Issue
1
Year of publication
1994
Pages
193 - 195
Database
ISI
SICI code
0022-4596(1994)110:1<193:IIIBEO>2.0.ZU;2-L
Abstract
We have successfully intercalated iodine between the Bi-O layers of th e semiconducting Bi2Sr2Y0.5Ca0.5Cu2O8+delta. X-ray diffraction and the rmogravimetric analysis confirmed the formation of a stage-1 intercala ted compound, IBi2Sr2Y0.5Ca0.5Cu2O8+delta. Upon intercalation, the com pound became superconducting, indicating there is a modest transfer of holes from iodine located in Bi-O layers to Cu-O sheets. (C) 1994 Aca demic Press, Inc.