J. Rehman et al., THE INFLUENCE OF SPONGE BORINGS ON ARAGONITE-TO-CALCITE INVERSION IN LATE PLEISTOCENE STROMBUS-GIGAS FROM GRAND-CAYMAN, BRITISH-WEST-INDIES, Journal of sedimentary research. Section A, Sedimentary petrology and processes, 64(2), 1994, pp. 174-179
Large, robust Strombus gigas lived in a variety of habitats in the Iro
nshore Lagoon that existed on Grand Cayman during the Late Sangamon hi
ghstand, approximately 125,000 years ago. Some well-preserved shells a
re still entirely aragonitic, whereas others have been transformed com
pletely to calcite. Permeability of the host rock and sponge-boring in
tensity were the most important controls on the extent of aragonite-to
-calcite inversion. Sponge borings played a critical role in the inver
sion process because they provided conduits through which the reactive
diagenetic fluids could penetrate the dense gastropod skeleton. Each
boring acted as a nucleus from which inversion fronts could spread int
o the shell. As a result, the radial fabric of the neomorphic calcite
crystals around the sponge borings contrasts sharply with the mosaic o
f equant calcite that formed in areas devoid of sponge borings. It see
ms that bioerosion is, at least on a local scale, as important as othe
r factors in controlling the meteoric alteration of carbonate sediment
. The deltaO-18 values of neomorphic calcite (-7.1 parts per thousand
to -4.9 parts per thousand), approximately 3 parts per thousand more d
epleted in O-18 than the original aragonite, confirm the role of meteo
ric water in the aragonite-to-calcite transformation. DeltaC-13 values
of the diagenetic calcite (+0.2 parts per thousand to +4.5 parts per
thousand) are similar to those in the original aragonite, suggesting t
hat the former was inherited from the latter.