SYNTHESIS AND STRUCTURE ELUCIDATION OF XY-ENDO-TRICYCLO[5.2.1.0(2,6)]DECA-3,8-DIEN-5-ONES AND XY-ENDO-TRICYCLO[5.2.1.0(2,6)]DECA-3,8-DIEN-5-ONES

Authors
SURI SC CABRERA AC WUCHERER EJ RODGERS SL
Citation
Sc. Suri et al., SYNTHESIS AND STRUCTURE ELUCIDATION OF XY-ENDO-TRICYCLO[5.2.1.0(2,6)]DECA-3,8-DIEN-5-ONES AND XY-ENDO-TRICYCLO[5.2.1.0(2,6)]DECA-3,8-DIEN-5-ONES, Synthetic communications, 27(5), 1997, pp. 841-851
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
5
Year of publication
1997
Pages
841 - 851
Database
ISI
SICI code
0039-7911(1997)27:5<841:SASEOX>2.0.ZU;2-N
Abstract
A mixture of 1-methyl- and tetrahydro-endo-1,4-methano-naphthalene-5,8 -diones (2 & 3) was chemically transformed into separable methyl subst ituted tricyclo[5.2.1.0(2,6)]decadienones 7, 8 & 9. The structure of 8 & 9 were elucidated via Cope rearrangement of their corresponding all ylic alcohols (10 & 11) to furnish 12 & 13 respectively.