SYNTHESIS OF A TETRAAZIDO-SUBSTITUTED 2-TETRAZENE FROM 1,5-CYCLOOCTADIENE AND IODINE AZIDE

Authors
ROSE B SCHOLLMEYER D MEIER H
Citation
B. Rose et al., SYNTHESIS OF A TETRAAZIDO-SUBSTITUTED 2-TETRAZENE FROM 1,5-CYCLOOCTADIENE AND IODINE AZIDE, Liebigs Annalen, (2), 1997, pp. 409-412
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Liebigs Annalen → ACNP
ISSN journal
09473440
Issue
2
Year of publication
1997
Pages
409 - 412
Database
ISI
SICI code
0947-3440(1997):2<409:SOAT2F>2.0.ZU;2-4
Abstract
In contrast to the addition of iodine azide to cyclooctene (1) or 1,3- cyclooctadiene (5), its reaction with 1,5-cyclooctadiene (12) leads ma inly to the surprisingly stable tetraazido-substituted 2-tetrazene 14. The structure of this was established by N-15-NMR studies and an X-ra y structural analysis. Treatment of 14 with hydrochloric acid yields t he diazido-substituted 9-azabicyclo[3.3.1]nonane 20.