P. Herve et Lkj. Vandamme, GENERAL RELATION BETWEEN REFRACTIVE-INDEX AND ENERGY-GAP IN SEMICONDUCTORS, Infrared physics & technology, 35(4), 1994, pp. 609-615
A review is given of existing relations and rules of thumb between ref
ractive index and energy pp in semiconductors. An error deviation was
calculated on more than one hundred materials. With only one set of fi
tting parameters, our model n2 = 1 + [A/(E(g) + B)]2, based on the cla
ssical oscillator theory, gives good fit except for IV-VI materials li
ke PbS, PbSe, PbTe. The constant A was found to have the same value as
the hydrogen ionization energy i.e. 13.6 eV and B = 3.4 eV.