Fibrillar polypyrroles have been prepared by electrodeposition through
honeycomb gamma-alumina membranes. The morphology has been extensivel
y studied using field-emission scanning electron microscopy. The rate
of fibre growth in several solvents has been measured by direct length
measurement. The occupation of the host membrane pores by polypyrrole
has been examined by ultramicrotome techniques. In extended polymeriz
ations, both solid rods and tubes are found.