PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .30. SIMULATION OF EQUILIBRIA IN SOLUBLE CHELATES OF BIVALENT METALS WITH POLY(METHACRYLOYLACETONE)

Authors
ZHELTVAI II MOVCHAN TI VOLOSHANOVSKII IS POMOGAILO AD
Citation
Ii. Zheltvai et al., PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .30. SIMULATION OF EQUILIBRIA IN SOLUBLE CHELATES OF BIVALENT METALS WITH POLY(METHACRYLOYLACETONE), Russian chemical bulletin, 42(6), 1993, pp. 1016-1019
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
6
Year of publication
1993
Pages
1016 - 1019
Database
ISI
SICI code
1066-5285(1993)42:6<1016:PAROMM>2.0.ZU;2-B
Abstract
The stability of chelates of several bivalent metals with poly(methacr yloylacetone) was determined by pH titration. Two models in which the fragment of a polymeric molecule in the coordination sphere of a metal was approximated by either a mono- or a bidentate ligand were conside red. Different mechanisms of complex formation were realized depending on the nature of M(II).