ELECTROCHEMICAL STUDY OF ALLYLBENZENE AND ALLYLCYCLOHEXADIENYL COMPLEXES OF RUTHENIUM

Authors
ZAITSEVA NN PETERLEITNER MG DENISOVICH LI PETROVSKII PV USTYNYUK NA
Citation
Nn. Zaitseva et al., ELECTROCHEMICAL STUDY OF ALLYLBENZENE AND ALLYLCYCLOHEXADIENYL COMPLEXES OF RUTHENIUM, Russian chemical bulletin, 42(6), 1993, pp. 1083-1085
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
6
Year of publication
1993
Pages
1083 - 1085
Database
ISI
SICI code
1066-5285(1993)42:6<1083:ESOAAA>2.0.ZU;2-6
Abstract
Cyclic voltammetry has been used to study the electrochemical behavior of RuCl(eta3-C3H5)(eta6-C6H6) (1), [Ru(PPh3) . (eta3-C3H5)(eta6-C6H6) ]BF4 (2), and Ru(PPh3) . (eta3-C3H5)eta5-C6H7) (3); the latter was pre pared by reacting 2 with LiAlH4. The reduction of 1 and 2 gives the 19 -electron complexes 1-. and 2., whereas oxidation of 3 gives the 17-el ectron complex 3+.. The reactivities of 1-., 2., and 3+. are discussed .