MITSUNOBU-LIKE PROCESSES WITH A NOVEL TRIPHENYLPHOSPHINE-CYCLIC SULFAMIDE BETAINE

Citation
Jl. Castro et al., MITSUNOBU-LIKE PROCESSES WITH A NOVEL TRIPHENYLPHOSPHINE-CYCLIC SULFAMIDE BETAINE, Journal of organic chemistry, 59(9), 1994, pp. 2289-2291
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00223263
Volume
59
Issue
9
Year of publication
1994
Pages
2289 - 2291
Database
ISI
SICI code
0022-3263(1994)59:9<2289:MPWANT>2.0.ZU;2-Q
Abstract
An unprecedented adduct 10 between triphenylphosphine (TPP) and 3,3-di methyl-1,2,5-thiadiazolidine 1,1-dioxide (8) is described, which can b e regarded las a stable source of the [Ph(3)P](+) species, and was uti lized to efficiently promote the coupling between alcohols and carboxy lic or nitrogen acids in a Mitsunobu-like manner.