PHOTOCHEMICAL-SYNTHESIS OF NEW TINORGANIC COMPOUNDS WITH ACTIVE SUBSTITUENTS ON TIN

Authors
LEONHARDT T LATSCHA HP
Citation
T. Leonhardt et Hp. Latscha, PHOTOCHEMICAL-SYNTHESIS OF NEW TINORGANIC COMPOUNDS WITH ACTIVE SUBSTITUENTS ON TIN, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(1), 1997, pp. 25-29
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
1
Year of publication
1997
Pages
25 - 29
Database
ISI
SICI code
0932-0776(1997)52:1<25:PONTCW>2.0.ZU;2-I
Abstract
By photochemically induced oxidative addition reactions the synthesis of some new tinorganic compounds was achieved. The reaction of dichlor o- and diiodotin with 1,2-diiodobenzene (1) induced by ultraviolet rad iation led to bis-(1-iodophenyl)diiodotin (2), bis-(1-iodophenyl)dichl orotin (3), 1-iodo-2-(trichlorotin)benzene (4) and 1-iodo-2-(triiodoti n)benzene (5). Iodosubstitution at the tin atom was also observed when dichlorotin was used as the starting compound. Analogous experiments with 1,2-dibromobenzene (6) and 1,2-dichloro- (7) gave no products.