A C-31 alkanediol isolated from the methanol extract of dried flower p
etals of Carthamus tinctorius was established to have the structure (6
R,8S and/or 6S,8R)-erythro-hentriacontane-6,8-diol by spectral and che
mical methods. Eleven other erythro-alkane-6,8-diols with carbon numbe
rs C-21, C-23, C-25, C-27-C-30 and C-32-C-35 were also isolated and ch
aracterized. This is the first report of the natural occurrence of sec
ondary erythro-alkane-beta-diols.