ON THE SYNTHESIS OF CH3C6H4S(O)(2)NCL2H- AND THE CRYSTAL-STRUCTURE OFCH3C6H4S(O)(2)NCL2(S BF6)

Authors
MINKWITZ R GARZAREK P PREUT H
Citation
R. Minkwitz et al., ON THE SYNTHESIS OF CH3C6H4S(O)(2)NCL2H- AND THE CRYSTAL-STRUCTURE OFCH3C6H4S(O)(2)NCL2(S BF6), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(1), 1997, pp. 88-94
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
1
Year of publication
1997
Pages
88 - 94
Database
ISI
SICI code
0932-0776(1997)52:1<88:OTSOCA>2.0.ZU;2-M
Abstract
The crystal structure of CH3C6H4S(O)(2)NCl2 is reported. Crystals are monoclinic, space group P2(1)/c, with n = 710.0(7), b = 1615.3(13), c = 867.2(7) pm, V = 988(2) pm(3) and Z = 4. The reaction with HF/SbF5 y ields CH3C6H4S(O)(2)NCl2H+SbF6- the first protonated dichloroamine sal t, its vibrational - and NMR spectra are discussed.