CRYSTAL-STRUCTURE OF 1,1,1-TRICHLORO-CYCL O-1-LAMBDA(6)-TUNGSTA-3,5-DITHIA-2,4,6-TRIAZINE, [WCL3(N3S2)](2)

Authors
KUNKEL F HARMS K DEHNICKE K
Citation
F. Kunkel et al., CRYSTAL-STRUCTURE OF 1,1,1-TRICHLORO-CYCL O-1-LAMBDA(6)-TUNGSTA-3,5-DITHIA-2,4,6-TRIAZINE, [WCL3(N3S2)](2), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(1), 1997, pp. 138-140
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
1
Year of publication
1997
Pages
138 - 140
Database
ISI
SICI code
0932-0776(1997)52:1<138:CO1O>2.0.ZU;2-3
Abstract
Single crystals of [WCl3(N3S2)](2) were obtained by the reaction of tr iphenyl-cyclo-1 lambda(5)-antimonia-2,4-dithia-3,5-diazine. SbPh(3)(N2 S2), with tungsten hexachloride in dichloromethane. Space group P2(1)/ n, Z = 2, lattice dimensions at -80 degrees C: a = 744.8(1), b = 923.5 (1), c = 1078.7(1) pm, beta = 94.43(1)degrees, R = 0.036. [WCl3(N3S2)] (2) forms centrosymmetric molecules with W2N2-fourmembered rings and p lanar cyclo-WN3S2 units.