A SIMPLIFIED MODEL FOR CATALYZED ISOBUTANE AUTOXIDATION - IMPLICATIONS FOR THE MECHANISM OF CATALYSIS BY HALOGENATED PORPHYRIN COMPLEXES

Authors
LABINGER JA
Citation
Ja. Labinger, A SIMPLIFIED MODEL FOR CATALYZED ISOBUTANE AUTOXIDATION - IMPLICATIONS FOR THE MECHANISM OF CATALYSIS BY HALOGENATED PORPHYRIN COMPLEXES, Catalysis letters, 26(1-2), 1994, pp. 95-99
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
26
Issue
1-2
Year of publication
1994
Pages
95 - 99
Database
ISI
SICI code
1011-372X(1994)26:1-2<95:ASMFCI>2.0.ZU;2-8
Abstract
A simple kinetic model shows that a radical-chain mechanism can accoun t for the high activity and selectivity found for oxidation of isobuta ne to t-butanol catalyzed by highly halogenated metalloporphyrins.