Zh. Peng et al., THE STRUCTURE OF BENZIMIDAZOLE CYANINE DYES, THEIR SPECTROSCOPY AND THEIR PERFORMANCE IN PHOTOGRAPHIC-EMULSIONS, Liebigs Annalen, (1), 1997, pp. 27-33
The multi-step synthesis of two benzimidazole trimethine cyanines as p
ossible green sensitizing dyes (Gs3-1, Gs3-2) is reported. Compounds w
ere characterized from UV-Vis, mass spectroscopic and NMR data. The ch
arge density distributions of the two compounds, calculated using the
semi-empirical MOPAC 93 package, are in agreement with assignments in
NMR spectroscopy. Sensitizing properties of the cyanine dyes were eval
uated in actual photographic T-grain emulsions.