CONSTRUCTION OF HIGHLY EFFICIENT MN-SALEN CATALYST FOR ASYMMETRIC EPOXIDATION OF CONJUGATED CIS-OLEFINS

Authors
SASAKI H IRIE R KATSUKI T
Citation
H. Sasaki et al., CONSTRUCTION OF HIGHLY EFFICIENT MN-SALEN CATALYST FOR ASYMMETRIC EPOXIDATION OF CONJUGATED CIS-OLEFINS, Synlett, (5), 1994, pp. 356-358
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
5
Year of publication
1994
Pages
356 - 358
Database
ISI
SICI code
0936-5214(1994):5<356:COHEMC>2.0.ZU;2-A
Abstract
On the basis of the newly proposed hypothesis on the olefin's approach to metal-oxo species, highly efficient (salen)manganese(III) complex (3) was synthesized as a catalyst for asymmetric epoxidation. With thi s catalyst, the highest level of enantioselectivity was realized in th e epoxidation of conjugated cis-olefins.