SYNTHESIS AND STRUCTURE OF NOVEL DERIVATIVES OF THIENO[2,3-B]THIOCINE- AN UNUSUAL PRODUCT OF INTRAMOLECULAR CYCLOADDITION OF HOMOMETHALLYLTHIO-5-METHYL-3-THIOPHENECARBONITRILE OXIDE
Mm. Krayushkin et al., SYNTHESIS AND STRUCTURE OF NOVEL DERIVATIVES OF THIENO[2,3-B]THIOCINE- AN UNUSUAL PRODUCT OF INTRAMOLECULAR CYCLOADDITION OF HOMOMETHALLYLTHIO-5-METHYL-3-THIOPHENECARBONITRILE OXIDE, Russian chemical bulletin, 42(7), 1993, pp. 1204-1208
etrahydro-6H-thieno[2,3-b]thiocino[4,5-c]isoxazole and hylene-6,7,8,9-
tetrahydro-5H-thieno[2,3-b]thiocine have been prepared for the first t
ime by the oxidation of 2-omega-alkenylthio-3-thiophenecarbaldoximes w
ith NaOCl. X-ray structural investigations of thieno[2,3-b]thiocine an
d homomethallylthio-5-methyl-3-thiophenecarbaldoxime have been carried
out.