INVESTIGATION OF THE ALKYLATION ABILITY OF SILYLATED NITROALCOHOLS

Authors
APASOV ET KALININ AV IOFFE SL TARTAKOVSKII VA
Citation
Et. Apasov et al., INVESTIGATION OF THE ALKYLATION ABILITY OF SILYLATED NITROALCOHOLS, Russian chemical bulletin, 42(7), 1993, pp. 1262-1263
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
7
Year of publication
1993
Pages
1262 - 1263
Database
ISI
SICI code
1066-5285(1993)42:7<1262:IOTAAO>2.0.ZU;2-6
Abstract
Beta-nitrosubstituted trimethylsilylated alcohols RCH2-O-SiMe3 [R = N( NO2)Me, C(NO2)Me2, C(NO2)2Me, C(NO2)3] have been studied. It has been shown that the trimethylsiloxy group is sufficiently reactive only in the N-nitro derivative in which it can be replaced by a chlorine atom or dimethylamino group upon the action of trimethylchlorosilane or pen tamethyldisilazane, respectively.