SILICON-CARBON UNSATURATED-COMPOUNDS .49. NICKEL-CATALYZED REACTIONS OF -2-(TRIMETHYLSILOXY)-1,1-BIS(TRIMETHYLSILYL)SILENE

Authors
OHSHITA J HASEBE H MASAOKA Y ISHIKAWA M
Citation
J. Ohshita et al., SILICON-CARBON UNSATURATED-COMPOUNDS .49. NICKEL-CATALYZED REACTIONS OF -2-(TRIMETHYLSILOXY)-1,1-BIS(TRIMETHYLSILYL)SILENE, Organometallics, 13(4), 1994, pp. 1064-1066
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
4
Year of publication
1994
Pages
1064 - 1066
Database
ISI
SICI code
0276-7333(1994)13:4<1064:SU.NRO>2.0.ZU;2-1
Abstract
Heating a benzene solution of adamantoyltris-(trimethylsilyl)silane (1 ) with a catalytic amount of Ni(PEt3)4 afforded the benzene adducts ri methylsiloxy)methyl]hexamethyl-2-phenyltrisilane and rimethylsiloxy)me thyl]hexamethyl-1-phenyltrisilane in 46 and 31 % yields. A similar nic kel-catalyzed reaction of 1 with dimethylphenylsilane produced 2-[adam antyl(trimethylsiloxy)methyl] pentamethyl-2-(trimethylsilyl)-1-phenylt risilane in 82% yield.