REDUCTION OF TERMINAL ALKYNES MEDIATED BY TRIS(2,2'-BIPYRIDINE)COBALT(I)

Authors
REITSMA DA KEENE FR
Citation
Da. Reitsma et Fr. Keene, REDUCTION OF TERMINAL ALKYNES MEDIATED BY TRIS(2,2'-BIPYRIDINE)COBALT(I), Organometallics, 13(4), 1994, pp. 1351-1354
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
4
Year of publication
1994
Pages
1351 - 1354
Database
ISI
SICI code
0276-7333(1994)13:4<1351:ROTAMB>2.0.ZU;2-2
Abstract
In buffered aqueous ethanolic solution, phenylacetylene is reduced to styrene by [Co(bpy)3]+ (bpy = 2,2'-bipyridine). In solutions of lower proton availability the predominant products were oligomeric, includin g coupled species such as 1,4-diphenylbutenyne.