THERMOLYSIS AND PHOTOLYSIS OF ARYLCHLORODIAZIRINES IN ALLYL BROMIDE

Authors
BONNEAU R GROBYS M LIU MTH HIMORI M FUKUSHIMA K IBATA T
Citation
R. Bonneau et al., THERMOLYSIS AND PHOTOLYSIS OF ARYLCHLORODIAZIRINES IN ALLYL BROMIDE, Research of chemical intermediates, 20(2), 1994, pp. 141-148
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Research of chemical intermediates → ACNP
ISSN journal
09226168
Volume
20
Issue
2
Year of publication
1994
Pages
141 - 148
Database
ISI
SICI code
0922-6168(1994)20:2<141:TAPOAI>2.0.ZU;2-R
Abstract
p-Chlorophenylchlorocarbene reacts with allyl bromide to form the expe cted cyclopropanes. In the case of p-nitrophenylchlorocarbene, a small amount of insertion product is also formed in addition to the cycload ducts. The formation of the insertion product is attributed to the att ack of the carbene on the bromine atom followed by intramolecular ally lic rearrangement.