The majority of hazardous waste is generated industrially, and the imp
ortance of industrial pollution prevention to economic and environment
al sustainability is now recognized. Sustainability can be evaluated u
sing benefit-risk analysis, globally and locally by public agencies an
d firms. To evaluate pollution prevention seriously, using benefit-ris
k analysis or other methods, the benefits of hazardous materials use i
n industry must be recognized. Pollution-prevention technologies in a
broad range of industries were reviewed as a part of research to devel
op benefit-risk methods. Ten basic functions served by hazardous mater
ials in industry were identified as binding, pigmentation, reactants,
reaction inhibition, catalysis, bleaching, mass deposition, mass remov
al, by-products, and end products. Pollution-prevention technologies w
ere associated with each function. The classification of technologies
offers a basis for development of general pollution-prevention approac
hes, and promotes transfer of technologies among industries in which h
azardous materials perform similar functions. Hazardous materials used
for mass transfer, and those generated as by-products, appear to repr
esent areas of opportunity for pollution-prevention research and devel
opment.