S. Reiss et al., EXPERIMENTAL-STUDY AND MODELING OF STRUCTURE FORMATION IN BURIED LAYERS AT ION-BEAM SYNTHESIS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 89(1-4), 1994, pp. 337-341
During ion beam synthesis of SIMOX structures a redistribution process
is responsible for the modification of the implanted O+ profile towar
ds a homogeneous buried layer of SiO2. This is known to be mainly due
to Ostwald ripening. The first approach of our study of this highly co
mplex system, both experimentally and theoretically, is devoted to the
substoichiometric concentration range representing the wings of stoic
hiometric layers. Our experiment shows that Ostwald ripening starts fr
om precipitates of comparable size, homogeneously distributed througho
ut the substoichiometric implanted layer. A computer simulation of Ost
wald ripening of such an initial distribution of precipitates results
in the self-organisation of structure in the precipitate distribution
which can be related to the experimentally observed two band structure
of precipitates. Thus it has been proven experimentally: (i) that the
two band structure of precipitates must not originate from preferred
precipitation in certain regions as proposed so far, and (ii) theoreti
cally that a structure formation in the precipitate distribution may a
rise from self-organisation during Ostwald ripening.