M. Touzet et al., THE CHARACTERIZATION OF DAMAGE IN SCC BY AN ELECTROCHEMICAL IMPEDANCEAND STATISTICAL STUDY OF MULTIPLE CRACKING, Corrosion science, 36(5), 1994, pp. 815-825
To build a realistic predictive model, it is essential to understand h
ow the damage is developed. The evolution of this damage on 304L steel
in Scheil reagent during slow strain rate tests has been studied for
4 various strain rates. An observation of the distribution of crack tr
aces (number, size and morphology) has shown that the damage is closel
y linked to the strain rate. Interrupted CERTs have been realised for
two strain rates. For each strain rate, electrochemical impedance meas
urements at fixed frequency (100 mHz) and histograms of the distributi
on of the crack traces have been carried out. The linked use of two te
chniques to characterize the damage in stress corrosion studies gives
very interesting results. The evolution of the phase of the electroche
mical impedance is closely linked to the initiation rate of cracks. De
nsity of cracks that have reached a given size could be a new definiti
on of the critical damage in stress corrosion studies when multiple cr
acks exist.