ELECTRONIC-SPECTRA AND PHOTOCHEMISTRY OF TRICHLOROSTANNYL COMPLEXES OF RHODIUM(III) AND PLATINUM(II)

Authors
PAWLOWSKI V KUNKELY H VOGLER A
Citation
V. Pawlowski et al., ELECTRONIC-SPECTRA AND PHOTOCHEMISTRY OF TRICHLOROSTANNYL COMPLEXES OF RHODIUM(III) AND PLATINUM(II), Coordination chemistry reviews, 132, 1994, pp. 23-28
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Coordination chemistry reviews → ACNP
ISSN journal
00108545
Volume
132
Year of publication
1994
Pages
23 - 28
Database
ISI
SICI code
0010-8545(1994)132:<23:EAPOTC>2.0.ZU;2-9
Abstract
The absorption spectra of [Rh(SnCl3)4Cl2]3- and [Pt(SnCl3)5]3- are cha racterized by a similar band pattern. It is suggested that the absorpt ion spectra are dominated by bands which are assigned to intraligand t ransitions. While solid (NBu4)3[Pt(SnCl3)5] shows a low-temperature em ission the rhodium complex is not luminescent. Both complex anions are light sensitive in acetonitrile solution. They undergo an efficient p hotosubstitution of the trichlorostannyl ligand.