BOND ACTIVATION BY MLCT EXCITATION OF ORGANOMETALLIC COMPOUNDS - PROMPT CO-PHOTODISSOCIATION FROM [CR(CO)4BPY]

Authors
VLCEK A VICHOVA J HARTL F
Citation
A. Vlcek et al., BOND ACTIVATION BY MLCT EXCITATION OF ORGANOMETALLIC COMPOUNDS - PROMPT CO-PHOTODISSOCIATION FROM [CR(CO)4BPY], Coordination chemistry reviews, 132, 1994, pp. 167-174
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Coordination chemistry reviews → ACNP
ISSN journal
00108545
Volume
132
Year of publication
1994
Pages
167 - 174
Database
ISI
SICI code
0010-8545(1994)132:<167:BABMEO>2.0.ZU;2-L
Abstract
Dissociation of an axial CO ligand from Cr(CO)4bpy under irradiation i nto the MLCT absorption band is a prompt process that takes place from directly excited vibronic levels of the 1MLCT state. Qualitative mode l of such processes based on a vibronic coupling between MLCT and LF s tates that activates promoting asymmetric vibration is proposed.