ZNI2 CATALYZED [2-BUTYN-2-ONE - CONFIRMATION OF A CYCLOBUTENE BY-PRODUCT FORMATION(2] VERSUS [3+2] CYCLOADDITION OF AN ALLYLTRIMETHYLSILANEWITH 3)

Authors
MONTI H AUDRAN G LEANDRI G MONTI JP
Citation
H. Monti et al., ZNI2 CATALYZED [2-BUTYN-2-ONE - CONFIRMATION OF A CYCLOBUTENE BY-PRODUCT FORMATION(2] VERSUS [3+2] CYCLOADDITION OF AN ALLYLTRIMETHYLSILANEWITH 3), Tetrahedron letters, 35(19), 1994, pp. 3073-3076
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
19
Year of publication
1994
Pages
3073 - 3076
Database
ISI
SICI code
0040-4039(1994)35:19<3073:ZC[-CO>2.0.ZU;2-C
Abstract
NMR experiments unequivocally show that the by-product obtained from t he ZnI2-promoted reaction of an allyltrimethylsilane with 3-butyn-2-on e is a [2+2] cycloaddition compound. This fact corroborates our previo usly described assignment. In the experimental conditions used, the re action occurs without 13-silyl shift.