ASYMMETRIC TRIFLUOROMETHYLATION OF ALDEHYDES AND KETONES WITH TRIFLUOROMETHYLTRIMETHYSILANE CATALYZED BY CHIRAL QUATERNARY AMMONIUM FLUORIDES

Authors
ISEKI K NAGAI T KOBAYASHI Y
Citation
K. Iseki et al., ASYMMETRIC TRIFLUOROMETHYLATION OF ALDEHYDES AND KETONES WITH TRIFLUOROMETHYLTRIMETHYSILANE CATALYZED BY CHIRAL QUATERNARY AMMONIUM FLUORIDES, Tetrahedron letters, 35(19), 1994, pp. 3137-3138
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
19
Year of publication
1994
Pages
3137 - 3138
Database
ISI
SICI code
0040-4039(1994)35:19<3137:ATOAAK>2.0.ZU;2-O
Abstract
The trifluoromethylation of aldehydes and ketones with trifluoromethyl trimethylsilane catalyzed by chiral quarternary ammmonium fluorides wa s carried out enantioselectively to give optically active 1-substitute d-2,2,2-trifluoroethanols.