TOWARDS THE SYNTHESIS OF THE PUTATIVE REACTION INTERMEDIATE IN THE KDO8P SYNTHASE-CATALYZED REACTION - SYNTHESIS AND EVALUATION OF 3-DEOXY-D-MANNO-2-OCTULOSONATE-2-PHOSPHATE
A. Kohen et al., TOWARDS THE SYNTHESIS OF THE PUTATIVE REACTION INTERMEDIATE IN THE KDO8P SYNTHASE-CATALYZED REACTION - SYNTHESIS AND EVALUATION OF 3-DEOXY-D-MANNO-2-OCTULOSONATE-2-PHOSPHATE, Tetrahedron letters, 35(19), 1994, pp. 3179-3182
The new compounds alpha- and beta-Kdo 2-phosphate (8 and 9) were synth
esized in order to probe the introduction of the phosphate group at th
e anomeric center of Kdo. This method was used towards the synthesis o
f the putative bisphosphate intermediate 4 in Kdo8P synthase-catalyzed
reaction.