Level populations and line intensities have been calculated in a 40-le
vel model of Fe XIV which includes the configurations 3p3 and 3s3p3d.
The results have been compared against intensities of weaker, unidenti
fied, or tentatively classified lines in published solar line lists in
cluding a recent GSFC/SERTS high-resolution list, and in presently mea
sured archival NRL/S082A active region spectra. Seven new lines are id
entified as Fe XIV transitions; five other observed, unidentified line
s are considered to be Fe XIV transitions on the basis of wave-length
coincidence, but require further observations to obtain photometric in
tensities for verification; one line at 216.93 angstrom is shown to be
due to some other ion than Fe XIV. In addition, a unique forbidden in
frared (congruent-to 1.25 mum) line originating in the high metastable
level 3s3p3d(F-4(9/2)) is found to have an unusual intensity dependen
ce on electron density.