APPROACHES TO WATER-SOLUBLE PHOSPHINES .2. FREE-RADICAL ADDITION-REACTIONS OF PHENYLPHOSPHINES

Authors
HEESCHEWAGNER K MITCHELL TN
Citation
K. Heeschewagner et Tn. Mitchell, APPROACHES TO WATER-SOLUBLE PHOSPHINES .2. FREE-RADICAL ADDITION-REACTIONS OF PHENYLPHOSPHINES, Journal of organometallic chemistry, 468(1-2), 1994, pp. 99-106
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
468
Issue
1-2
Year of publication
1994
Pages
99 - 106
Database
ISI
SICI code
0022-328X(1994)468:1-2<99:ATWP.F>2.0.ZU;2-9
Abstract
Free radical additions of diphenylphosphine, phenylphosphine and ethyl enebis(phenylphosphine) to the following species are described: alkyno ls, alkyne ethers, unsaturated carboxylic acids and esters and beta-la ctones. In a number of cases, these lead to water-soluble phosphines. NMR spectroscopic characterization of all new products has been carrie d out.