SYNTHESIS, ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL STUDIES OF METAL-FREE 2,9,16,23-TETRAFERROCENYLPHTHALOCYANINE

Authors
JIN Z NOLAN K MCARTHUR CR LEVER ABP LEZNOFF CC
Citation
Z. Jin et al., SYNTHESIS, ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL STUDIES OF METAL-FREE 2,9,16,23-TETRAFERROCENYLPHTHALOCYANINE, Journal of organometallic chemistry, 468(1-2), 1994, pp. 205-212
Citations number
56
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
468
Issue
1-2
Year of publication
1994
Pages
205 - 212
Database
ISI
SICI code
0022-328X(1994)468:1-2<205:SEASSO>2.0.ZU;2-6
Abstract
Cyclic voltammetric, differential pulse voltammetric and spectroelectr ochemical methods have been used to study the newly synthesized metal- free 2,9,16,23-tetraferrocenylphthalocyanine in dichloroethane. Two re versible reduction peaks are obtained, corresponding to electrode reac tions of the phthalocyanine ring. The multiple ferrocenyl redox center s are oxidized at one potential. The electronic spectra are reported f or this species in different oxidation states.