CONTROL OF PRODUCT SELECTIVITY FOR THE EPOXIDATION OF ALLYL ALCOHOL BY VARIATION OF THE ACIDITY OF THE CATALYST TS-1

Authors
HUTCHINGS GJ LEE DF
Citation
Gj. Hutchings et Df. Lee, CONTROL OF PRODUCT SELECTIVITY FOR THE EPOXIDATION OF ALLYL ALCOHOL BY VARIATION OF THE ACIDITY OF THE CATALYST TS-1, Journal of the Chemical Society, Chemical Communications, (9), 1994, pp. 1095-1096
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1994
Pages
1095 - 1096
Database
ISI
SICI code
0022-4936(1994):9<1095:COPSFT>2.0.ZU;2-A
Abstract
The acidity of TS-1 controls the product selectivity for the epoxidati on of allyl alcohol with H2O2; base treatment of TS-l enhances the sel ectivity to glycidol whereas incorporation of Bronsted acid sites enha nces the selectivity to the products of solvolysis ring opening reacti ons.