REGIOCHEMICAL CONTROL IN REDUCTIVE ELIMINATION OF (ETA-3-CROTYL)(ARYL)PALLADIUM(II) COMPLEXES

Authors
KUROSAWA H SHIBA K HIRAKO K KAKIUCHI K IKEDA I
Citation
H. Kurosawa et al., REGIOCHEMICAL CONTROL IN REDUCTIVE ELIMINATION OF (ETA-3-CROTYL)(ARYL)PALLADIUM(II) COMPLEXES, Journal of the Chemical Society, Chemical Communications, (9), 1994, pp. 1099-1100
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1994
Pages
1099 - 1100
Database
ISI
SICI code
0022-4936(1994):9<1099:RCIREO>2.0.ZU;2-G
Abstract
The electronic character, of PR(3) ligand controls the relative rates of the geometrical isomerisation and the cis reductive elimination of eta(3)-crotyl(aryl)palladium complexes; more electron-withdrawing phos phites lead to selective bond formation at the more substituted allyl end.