An. Belsky et al., EXPERIMENTAL-STUDY OF THE EXCITATION THRESHOLD OF FAST INTRINSIC LUMINESCENCE OF CSI, Physical review. B, Condensed matter, 49(18), 1994, pp. 13197-13200
A type of intrinsic luminescence in crystals has been revealed. The ex
citation threshold of well-known fast intrinsic luminescence of CsI (3
00 nm band) has been obtained from the excitation spectrum measured in
the photon-energy range 5-125 eV at 300 K using synchrotron radiation
. The excitation starts from an energy of about 20 eV and exponentiall
y increases up to the 4d I-ionization energy (approximately 50 eV). Su
ch high-energy broad threshold is not typical for any conventional mec
hanisms of luminescence excitation. We attribute this type of luminesc
ence to the emission center, which is created by the interaction of se
veral elementary excitations produced in the process of relaxation of
a primary excitation. The possible role of 4d I- core levels is discus
sed. The nanosecond decay kinetics of this luminescence is nonexponent
ial for all energies of excitation.