The reflection of metastable argon atoms from evanescent waves produce
d by total internal reflection and surface-plasmon excitation is inves
tigated. We study the departure from ideal specular reflection by comp
aring our experimental results with a Monte Carlo simulation of the re
flection process. The observed broadening of the reflection beam was f
ound to be caused predominantly by fluctuations of the dipole force. W
e show that the surface plasmon produces significant enhancement of th
e evanescent-wave intensity without degrading the quality of reflectio
n. In addition, the number of spontaneous emissions occurring during t
he reflection process was investigated by comparing the reflectivity o
f evanescent-wave mirrors based on open and closed transitions in argo
n. An open-transition mirror selectively reflects atoms which do not u
ndergo spontaneous emission. For a large detuning, the average number
of spontaneous emissions for reflected atoms was < 0.11.