SYNTHESIS AND STRUCTURAL STUDIES OF LAYERED ALUMINUM PHENYLPHOSPHONATE

Authors
HAKY JE BRADY JB DANDO N WEAVER D
Citation
Je. Haky et al., SYNTHESIS AND STRUCTURAL STUDIES OF LAYERED ALUMINUM PHENYLPHOSPHONATE, Materials research bulletin, 32(3), 1997, pp. 297-303
Citations number
19
Categorie Soggetti
Material Science
Journal title
Materials research bulletin → ACNP
ISSN journal
00255408
Volume
32
Issue
3
Year of publication
1997
Pages
297 - 303
Database
ISI
SICI code
0025-5408(1997)32:3<297:SASSOL>2.0.ZU;2-Q
Abstract
A new aluminum phenylphosphonate compound with the formula AlH(C6H5PO3 )(2) . H2O was obtained by refluxing a mixture of aluminum nitrate and excess phenylphosphonic acid in water. The compound was characterized by elemental analysis, thermal gravimetry, X-ray powder diffraction, and Al-27 nuclear magnetic resonance spectroscopy. It has a pillared l ayered structure containing only octahedrally coordinated aluminum ato ms, with an interlayer spacing of similar to 15 Angstrom. Copyright (C ) 1997 Elsevier Science Ltd.