Ee. Aubanel et al., INTENSE-FIELD MOLECULAR-SPECTROSCOPY - VIBRATIONAL AND ROTATIONAL EFFECTS IN HARMONIC-GENERATION BY H-2+, Physical review. A, 49(5), 1994, pp. 3776-3787
We present results of a complete treatment of electronic, vibrational,
and rotational motion in numerical calculation of harmonic generation
(HG) of 1064-nm laser radiation by the H-2+ molecular ion for intensi
ties 10(13) less-than-or-equal-to I less-than-or-equal-to 10(14) W/cm2
. We show that efficient HG can be enhanced by suppression of photodis
sociation, a phenomenon which results from vibrational trapping in las
er-field-induced potential wells. The HG spectra exhibit peaks cluster
ed around even and odd harmonic orders. All peaks can be assigned to R
aman-like transitions between dressed eigenstates of the field-molecul
e system. Rotational excitation is shown to compete with HG. Thus harm
onic generation and photon scattering in molecules holds the promise o
f a potential diagnostic for molecular stabilization by intense laser
fields.