M. Kamata et T. Esaka, THERMODYNAMIC DESCRIPTIONS OF OXYGEN REDISTRIBUTION IN A NUCLEAR-FUELPELLET - HEAT OF TRANSPORT OF OXYGEN IN MIXED CONDUCTORS, Journal of Applied Electrochemistry, 24(5), 1994, pp. 390-395
Transport processes in a mixed conductor (e.g. a UO2 pellet) are rigor
ously described by using an irreversible thermodynamic approach and a
re-evaluation of the effect of thermoelectric power is carried out. Th
e results indicate that the oxygen redistribution can be interpreted a
s an electrochemical mass transport phenomenon caused by thermoelectri
c power. The validity of this interpretation is confirmed using experi
mental results from other sources.